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File: 082696_doc1_072.txt
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PHOSGENE
SECTION IV (continued)
Unusual Fire and Explosion Hazards: When heated to decomposition or on
contact with water or steam, it will react to produce toxic and corrosive
fumes (*Sax 1975).
NFPA Flammability Rating: 0
SECTION V - REACTIVITY DATA
Stability: Unstable:
Stable: Yes, in steel containers if dry (U.S. Army 1975,
p. 3-1)
Conditions to Avoid: Moisture (*Sax 1975)
Incompatibility (Materials to Avoid): Reacts violently with aluminum;
tert-butyl azido formate; 2,4-hexadiyn-l,6-diol; isopropyl alcohol;
potassium; sodium; hexafluoro isopropylidene; amino lithium; lithium (Sax
1984, p. 2211).
Hazardous Decomposition or Byproducts: When heated to decomposition or on
contact with water or steam, it will react to produce toxic and corrosive
} fumes (*Sax 1975).
Hazardous Polymerization: May Occur: Not Found
May Not Occur: Not Found
Conditions to Avoid: Not Found
-i SECTION VI - USE INFORMATION
Delayed-action military chemical agent (U.S. Army 1975, p. 3-1). Chemical
intermediate for toluene diisocyanate, methyl isocyanate, acyl chlorides,
diphenylmethane-4,4'-diisocyanate, chloroformate esters, diethyl carbonate,
dimethyl carbamoyl chloride, polymethylene polyphenylisocyanate,
polycarbonate resins (*SRI); aniline dyes (*Hamilton 1974); pesticides,
herbicides, dyes (Hawley 1981, p. 807).
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
(Steps to be Taken in Case Material is Released or Spilled)
Keep unnecessary people away; isolate hazard area and deny entry.
Stay upwind and keep Out of low areas. Ventilate closed spaces before
entering.
SECTION VIII- PROTECTIVE EQUIPMENT FOR EMERGENCY SITUATIONS
For emergency situations, wear a positive pressure, pressure-demand,
full facepiece self-contained breathing apparatus (SC3A) or pressure-
3 demand supplied air respirator with escape SCBA and a fully-encapsulating,
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