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File: 082696_doc1_057.txt
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MUSTARD GAS
SECTION IV (continued)
Unusual Fire and Explosion Hazards: Can be ignited by large explosive
charge. When heated to decomposition, emits highly toxic fumes of oxides
of sulfur and chlorine containing compounds. Reacts with water or steam to
produce toxic and corrosive fumes (*Sax 1975). Containers may rupture
violently in a rire (Student 1981, p. 358).
NFPA Flammability Rating: Not Found
SECTION V -- REACTIVITY DATA
Stability: Unstable: Yes; hydrolyzed in aqueous solution (*IARC
1972-1985)
Stable:
Conditions to Avoid: High heat; contact with acid or acid fumes (*Sax
1984, p. 482).
Incompatibility (Materials to Avoid): Incompatible with bleaching powder
(Sax 1984, p. 482). Reacts violently with oxidizing materials. Reacts
with water or steam to produce toxic and corrosive fumes (*Sax 1975).
Hazardous Decomposition or Byproducts: Emits highly toxic fumes of oxides
) of sulfur and chlorine containing compounds when heated to decomposition or
on contact with acid or acid fumes (*Sax 1974)
Hazardous Polymerization: May Occur: Not Found
May Not Occur: Not Found
Conditions to Avoid: Not Found
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SECTION VI-- USE INFORMATION
It has been used as a chemical warfare agent (*IARC 1972-1985) and as a
chemical intermediate. It is not produced commercially in the U.S. (*SRI).
SECTION VII-- PRECAUTIONS FOR SAFE HANDLING AND USE
(Steps to be Taken in Case Material is Released or Spilled)
To clean up a spill, cover with up to 15 percent calcium hypochloride.
Place in container; neutralize after 12 hours if necessary (*Rumack 1975 to
Present). Keep sparks, flames, and other sources of ignition away. Keep
material out of water sources and sewers. Attempt to stop leak if without
hazard. Use water spray to knock down vapors. Avoid breathing vapors and
bodily contact with the material. Keep upwind. Wash away any material
which may have contacted the body with copious amounts of soap and water.
Downwind evacuation must be considered (Student 1981, p. 358).
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